Dyeing
Dyeing is the process of adding color to textile products like fibers, yarns and fabrics.Dyeing is normally done in a special solution containing dyes and particular chemical material. After dyeing, dye molecules have uncut chemical bond with fiber molecules. The temperature and time controlling are two key factors in dyeing. There are mainly two classes of dye, natural and man-made.
The primary source of dye, historically, has generally been nature, with the dyes being extracted from animals or plants. Since the mid-18th century, however, humans have produced artificial dyes to achieve a broader range of colors and to render the dyes more stable to resist washing and general use. Different classes of dyes are used for different types of fiber and at different stages of the textile production process, from loose fibers through yarn and cloth to completed garments.
Acrylic fibers are dyed with basic dyes, while nylon and protein fibers such as wool and silk are dyed with acid dyes, and polyester yarn is dyed with disperse dyes. Cotton is dyed with a range of dye types, including vat dyes, and modern synthetic reactive and direct dyes.
The primary source of dye, historically, has generally been nature, with the dyes being extracted from animals or plants. Since the mid-18th century, however, humans have produced artificial dyes to achieve a broader range of colors and to render the dyes more stable to resist washing and general use. Different classes of dyes are used for different types of fiber and at different stages of the textile production process, from loose fibers through yarn and cloth to completed garments.
Acrylic fibers are dyed with basic dyes, while nylon and protein fibers such as wool and silk are dyed with acid dyes, and polyester yarn is dyed with disperse dyes. Cotton is dyed with a range of dye types, including vat dyes, and modern synthetic reactive and direct dyes.
History
Archaeologists have found evidence of textile dyeing dating back to the Neolithic period. The earliest surviving evidence of textile dyeing was found at the large Neolithic settlement at Çatalhöyük in southern Anatolia, where traces of red dyes, possibly from ochre, an iron oxide pigment derived from clay), were found. In China, dyeing with plants, barks, and insects has been traced back more than 5,000 years. Early evidence of dyeing comes from Sindh province in Pakistan, where a piece of cotton dyed with a vegetable dye was recovered from the archaeological site at Mohenjo-daro (3rd millennium BCE).[5] The dye used in this case was madder, which, along with other dyes such as indigo, was introduced to other regions through trade. Natural insect dyes such as Tyrian purple and kermes and plant-based dyes such as woad, indigo and madder were important elements of the economies of Asia and Europe until the discovery of man-made synthetic dyes in the mid-19th century. The first synthetic dye was William Perkin's mauveine in 1856, derived from coal tar. Alizarin, the red dye present in madder, was the first natural pigment to be duplicated synthetically in 1869 a development which led to the collapse of the market for naturally grown madder.The development of new, strongly colored synthetic dyes followed quickly, and by the 1870s commercial dyeing with natural dyestuffs was disappearing.
Methods
Dyes are applied to textile goods by dyeing from dye solutions and by printing from dye pastes.
Direct application
This section requires expansion. (June 2008)
The term "direct dye application" stems from some dyestuff having to be either fermented as in the case of some natural dye or chemically reduced as in the case of synthetic vat and sulfur dyes before being applied. This renders the dye soluble so that it can be absorbed by the fiber since the insoluble dye has very little substantivity to the fiber. Direct dyes, a class of dyes largely for dyeing cotton, are water soluble and can be applied directly to the fiber from an aqueous solution. Most other classes of synthetic dye, other than vat and surface dyes, are also applied in this way.
The term may also be applied to dyeing without the use of mordants to fix the dye once it is applied. Mordants were often required to alter the hue and intensity of natural dyes and improve color fastness. Chromium salts were until recently extensively used in dying wool with synthetic mordant dyes. These were used for economical high color fastness dark shades such as black and navy. Environmental concerns have now restricted their use, and they have been replaced with reactive and metal complex dyes that do not require mordant.
Direct application
This section requires expansion. (June 2008)
The term "direct dye application" stems from some dyestuff having to be either fermented as in the case of some natural dye or chemically reduced as in the case of synthetic vat and sulfur dyes before being applied. This renders the dye soluble so that it can be absorbed by the fiber since the insoluble dye has very little substantivity to the fiber. Direct dyes, a class of dyes largely for dyeing cotton, are water soluble and can be applied directly to the fiber from an aqueous solution. Most other classes of synthetic dye, other than vat and surface dyes, are also applied in this way.
The term may also be applied to dyeing without the use of mordants to fix the dye once it is applied. Mordants were often required to alter the hue and intensity of natural dyes and improve color fastness. Chromium salts were until recently extensively used in dying wool with synthetic mordant dyes. These were used for economical high color fastness dark shades such as black and navy. Environmental concerns have now restricted their use, and they have been replaced with reactive and metal complex dyes that do not require mordant.
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